The kinetics of propene and hexenepolymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states

Literature Information

Publication Date 2004-02-05
DOI 10.1039/B314845A
Impact Factor 6.222
Authors

Fuquan Song, Roderick D. Cannon, Manfred Bochmann


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Abstract

Whereas the rates of propene polymerisation catalysed by zirconocene ion pairs are strongly anion-dependent, hexene polymerisations are not; the findings demonstrate the existence of very different kinetic regimes for two closely related reactions.

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