Tetraplatinum precursors for supramolecular assemblies: syntheses, crystal structures, and stereoselective self-assemblies of [Pt4(μ-OCOCH3)6(κ4-N4-DArBp)] (DArBp = 1,3-bis(arylbenzamidinate)propane)
Literature Information
Publication Date
2007-05-22
DOI
10.1039/B703730A
Impact Factor
6.222
Authors
Masato Ohashi, Akihiro Yagyu, Tsuneaki Yamagata, Kazushi Mashima
View Original
Abstract
Treatment of the cisoid-capped complex [Pt4(μ-OCOCH3)6(κ4-N4-DAr′Bp)] (2a), which was obtained from the reaction of [Pt4(μ-OCOCH3)8] (1) with Na2DtBuPhBp (DtBuPhBp = 1,3-bis(para-tert-butylphenylbenzamidinate)propane), with an equimolar amount of 1,1′-ferrocenedicarboxylic acid undergoes a stereoselective self-assembly to afford an indented-quadrangle tetramer [Pt4(μ-OCOCH3)4(κ4-N4-DtBuPhBp){Fe(C5H4COO)2}]4 (4) as a single diastereomer.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
1-(3-Bromo-4-fluorophenyl)methanamine hydrochloride (1:1)
CAS Number:
202865-68-7
Molecular Formula:
C7H8BrClFN
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