Mechanistical studies on the formation of isotopomers of hydrogen peroxide (HOOH), hydrotrioxy (HOOO), and dihydrogentrioxide (HOOOH) in electron-irradiated H218O/O2 ice mixtures

Literature Information

Publication Date 2007-03-13
DOI 10.1039/B700814G
Impact Factor 3.676
Authors

David Jewitt, Ralf I. Kaiser


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Abstract

In order to investigate the chemical reactions inside water–oxygen ice mixtures in extreme environments, and to confirm the proposed reaction mechanisms in pure water ice, we conducted a detailed infrared spectroscopy and mass spectrometry study on the electron irradiation of H218O/O2 ice mixtures. The formation of molecular hydrogen, isotopically substituted oxygen molecules 18O18O and 16O18O, ozone (16O16O16O, 16O16O18O, and 16O18O16O), hydrogen peroxide (H18O18OH, H16O16OH and H16O18OH), hydrotrioxy (HOOO), and dihydrogentrioxide (HOOOH) were detected. Kinetic models and reaction mechanisms are proposed to form these molecules in water and oxygen-rich solar system ices.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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