Mechanistical studies on the formation of isotopomers of hydrogen peroxide (HOOH), hydrotrioxy (HOOO), and dihydrogentrioxide (HOOOH) in electron-irradiated H218O/O2 ice mixtures
Literature Information
David Jewitt, Ralf I. Kaiser
In order to investigate the chemical reactions inside water–oxygen ice mixtures in extreme environments, and to confirm the proposed reaction mechanisms in pure water ice, we conducted a detailed infrared spectroscopy and mass spectrometry study on the electron irradiation of H218O/O2 ice mixtures. The formation of molecular hydrogen, isotopically substituted oxygen molecules 18O18O and 16O18O, ozone (16O16O16O, 16O16O18O, and 16O18O16O), hydrogen peroxide (H18O18OH, H16O16OH and H16O18OH), hydrotrioxy (HOOO), and dihydrogentrioxide (HOOOH) were detected. Kinetic models and reaction mechanisms are proposed to form these molecules in water and oxygen-rich solar system ices.
Recommended Journals
Related Literature
Sequence regulation in living anionic terpolymerization of styrene and two categories of 1,1-diphenylethylene (DPE) derivatives
Lincan Yang, Heyu Shen, Li Han, Hongwei Ma, Chao Li, Lan Lei, Songbo Zhang, Pibo Liu, Yang Li
DOI: 10.1039/D0PY00731E
Synthesis of polyethers from epoxides via a binary organocatalyst system
Ge-Ge Gu, Li-Yang Wang, Rong Zhang, Tian-Jun Yue, Bai-Hao Ren, Wei-Min Ren
DOI: 10.1039/D1PY01085A
Biobased poly(ester-co-glycoside) from reactive natural Brønsted acidic deep eutectic solvent analogue
Gabriel Duaux, Etienne Fleury, Daniel Portinha
DOI: 10.1039/D1PY00990G
Intrinsic flame retardant phosphonate-based vitrimers as a recyclable alternative for commodity polymers in composite materials
Jens C. Markwart, Alexander Battig, Tobias Urbaniak, Katharina Haag, Katharina Koschek, Bernhard Schartel, Frederik R. Wurm
DOI: 10.1039/D0PY00275E
Semiaromatic polyamides with enhanced charge carrier mobility
Bilal Özen, Nicolas Candau, Cansel Temiz, Ferdinand C. Grozema, Grégory Stoclet, Christopher J. G. Plummer, Holger Frauenrath
DOI: 10.1039/D1PY01203G
The influences of monomer structure and solvent on the radical copolymerization of tertiary amine and PEGylated methacrylates
Priscila Quiñonez-Angulo, Robin A. Hutchinson, Ángel Licea-Claveríe, Enrique Saldívar-Guerra, Iván Zapata-González
DOI: 10.1039/D1PY00750E
Structure–property relations of amphiphilic poly(furfuryl glycidyl ether)-block-poly(ethylene glycol) macromonomers at the air–water interface
Alexander Holm, Alexander Southan, Curtis W. Frank
DOI: 10.1039/D0PY00697A
Impact of multi-vinyl taxogen dimensions on high molecular weight soluble polymer synthesis using transfer-dominated branching radical telomerisation
Oliver B. Penrhyn-Lowe, Sean Flynn, Savannah R. Cassin, Samuel Mckeating, Sarah Lomas, Stephen Wright, Pierre Chambon, Steve P. Rannard
DOI: 10.1039/D1PY01103K
On the limitations of cationic polymerization of vinyl monomers in aqueous dispersed media
Aurélie Destephen
DOI: 10.1039/D1PY01046H
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














![(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure (2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure](https://static.chemtradehub.com/structs/109/1093085-91-6-3382.webp)