Demonstration of the optical limiting effect for an hemiporphyrazine

Literature Information

Publication Date 2006-05-03
DOI 10.1039/B601591C
Impact Factor 6.222
Authors

Danilo Dini, Mario J. F. Calvete, Michael Hanack, Vincenzo Amendola, Moreno Meneghetti


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Abstract

The hemiporphyrazine complex 9,22-bis(dibutoxy)hemiporphyrazinato chloroindium(III) (1) is one of the few examples for this class of compounds, which displays the nonlinear optical effect of reverse saturable absorption for nanosecond laser pulses in the visible spectrum. The high linear transmission combined with the fast switching into a strongly absorbing excited state in the same spectral range (400–650 nm), renders the studied hemiporphyrazine an ideal material for the passive shuttering of pulsed radiations.

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