Theoretical modeling of the valence UV spectra of 1,2,3-triazine and uracil in solution

Literature Information

Publication Date 2006-02-24
DOI 10.1039/B515648C
Impact Factor 3.676
Authors

Andrea Amadei, Nico Sanna, Andrea Grandi, Giovanni Chillemi, Alfredo Di Nola, Marco D’Abramo, Massimiliano Aschi


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Abstract

Assessment of the perturbed matrix method (PMM) ability in reproducing valence UV absorption spectra is carried out on two model systems: 1,2,3-triazine in methanol solution and uracil in water solution. Results show that even using the simplest definition of the quantum center, i.e. the portion of the system explicitly treated quantum mechanically, PMM provides rather good results. This paper further confirms the possibility of using PMM as a theoretical–computational tool, complementary to other methodologies, for addressing the electronic properties in molecular systems of high complexity.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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