Enantioselective conjugate addition of phenylboronic acid to enones catalysed by a chiral tropos/atropos rhodium complex at the coalescence temperature

Literature Information

Publication Date 2005-09-21
DOI 10.1039/B508832A
Impact Factor 6.222
Authors

Chiara Monti, Cesare Gennari, Umberto Piarulli


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Abstract

A highly enantioselective rhodium-catalysed conjugate addition of phenylboronic acid to cyclic enones has been achieved using a dynamic library of chiral phosphorus ligands; the tropos/atropos nature of the ligands in the rhodium complex has been characterised via31P-NMR.

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