Pentacoordinated germanium in AST zeolite synthesised in fluoride media. A 19F NMR validated computational study
Literature Information
German Sastre, Angeles Pulido, Avelino Corma
A computational study shows that Ge is pentacoordinated in the double four rings (D4R) of Si/Ge AST zeolites; the calculated chemical shifts of F-D4R containing 8Si, 7Si1Ge and 8Ge reproduce the trends of 19F NMR experiments.
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![7-Amino-5-methyl-5,7-dihydro-6H-dibenzo[b,d]azepin-6-one hydrochloride (1:1) structure 7-Amino-5-methyl-5,7-dihydro-6H-dibenzo[b,d]azepin-6-one hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/209/209984-32-7-9912.webp)
