A click chemistry approach to the efficient synthesis of polyoxometalate–polymer hybrids with well-defined structures

Literature Information

Publication Date 2012-01-18
DOI 10.1039/C2PY00546H
Impact Factor 5.582
Authors

Min-Biao Hu, Nan Xia, Wei Yu, Chi Ma, Jing Tang, Zhan-Yao Hou, Ping Zheng, Wei Wang


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Abstract

In this study a click chemistry approach was used to synthesize polyoxometalate–polymer hybrids with well-defined structures. The starting materials were a two-azido-containing organosilyl derivative of a Wells-Dawson-type polyoxometalate and a propargyl-terminated poly(ε-caprolactone). The clicking reaction between the azido groups and alkynyl groups was found to be very efficient and the structures of the hybrids were well-defined. This breakthrough will promote a great development in the synthesis of various polyoxometalate–polymer hybrids and broaden their potential application.

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Polymer Chemistry

Polymer Chemistry
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