Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones: an efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems

Literature Information

Publication Date 2004-12-01
DOI 10.1039/B413842B
Impact Factor 6.222
Authors

Yoshihiro Miyake, Mo Wu, M. Jalilur Rahman, Masahiko Iyoda


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Abstract

The electron transfer reaction from Lipshutz cuprates, which can be easily prepared from aryl bromides, to 1,4-benzoquinones was found to proceed smoothly, affording either the corresponding homo-coupling products, in modest to excellent yields, or macrocyclic products selectively.

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