Manganese N-confused porphyrin reactivity: CH bond activation and meso carbon reduction
Literature Information
John D. Harvey, Christopher J. Ziegler
Manganese N-confused porphyrins activate C–C and C–H bonds upon heating or air oxidation; the dimer complex [Mn(NCTPP)]2 is reduced at two meso positions, and the pyridine coordinated monomer breaks the internal C–H bond upon heating or exposure to oxygen.
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