Manganese N-confused porphyrin reactivity: CH bond activation and meso carbon reduction

Literature Information

Publication Date 2003-10-22
DOI 10.1039/B310522A
Impact Factor 6.222
Authors

John D. Harvey, Christopher J. Ziegler


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Abstract

Manganese N-confused porphyrins activate C–C and C–H bonds upon heating or air oxidation; the dimer complex [Mn(NCTPP)]2 is reduced at two meso positions, and the pyridine coordinated monomer breaks the internal C–H bond upon heating or exposure to oxygen.

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