Reactions of phenyldimethylsilyllithium with β-N,N-dimethylaminoenones
Literature Information
Ian Fleming, Elena Marangon, Chiara Roni, Matthew G. Russell, Sandra Taliansky Chamudis
Phenyldimethylsilyllithium reacts with the β-N,N-dimethylaminoenones 1 and 7, with the enal 5, and with ethyl β-N,N-dimethylaminoacrylate 9 to give the corresponding α,β-unsaturated carbonyl compounds with a β-phenyldimethylsilyl group, but in the last case only when the reaction mixture is given a mysteriously brief treatment with methyl iodide before workup.
Related Literature
Quantitative analysis of ACE2 binding to coronavirus spike proteins: SARS-CoV-2 vs. SARS-CoV and RaTG13
Zhendong Li
DOI: 10.1039/D1CP01075A
Effects of molecular shape on alcohol aggregation and water hydrogen bond network behavior in butanol isomer solutions
Seungeui Choi, Saravanan Parameswaran, Jun-Ho Choi
DOI: 10.1039/D1CP00634G
Bayesian phase difference estimation: a general quantum algorithm for the direct calculation of energy gaps
Chikako Sakai, Kazuo Toyota, Kazunobu Sato, Daisuke Shiomi
DOI: 10.1039/D1CP03156B
Simple lattice model of self-assembling metal–organic layers of pyridyl-substituted porphyrins and copper on Au(111) surface
Anastasiia I. Fadeeva, Vitaly A. Gorbunov, Alexander V. Myshlyavtsev
DOI: 10.1039/D1CP03111B
Salt bridge dynamics in protein/DNA recognition: a comparative analysis of Elk1 and ETV6
Tam D. Vo, Amelia L. Schneider
DOI: 10.1039/D1CP01568K
Time-resolved observations of vibrationally excited NO X 2Π (v′) formed from collisional quenching of NO A 2Σ+ (v = 0) by NO X 2Π: evidence for the participation of the NO a 4Π state
James D. Fletcher, Lucia Lanfri, Grant A. D. Ritchie, Gus Hancock, Meez Islam, Graham Richmond
DOI: 10.1039/D1CP03360C
Fabrication and photocatalytic activity of graphitic-C3N4 quantum dots-decorated basic zinc carbonate prepared by a co-precipitation method
Ping Zhao, Bo Jin, Qingchun Zhang, Rufang Peng
DOI: 10.1039/D1CP03466A
The necessity of periodic boundary conditions for the accurate calculation of crystalline terahertz spectra
Peter A. Banks, Luke Burgess, Michael T. Ruggiero
DOI: 10.1039/D1CP02496E
Spectroscopic investigations of electron and hole dynamics in MAPbBr3 perovskite film and carrier extraction to PEDOT hole transport layer
Mojgan Kouhnavard, Yifan Diao, Pratim Biswas
DOI: 10.1039/D1CP00658D
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![1-(1-Benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-benzo[d]imidazol-2(3H)-one structure 1-(1-Benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-benzo[d]imidazol-2(3H)-one structure](https://static.chemtradehub.com/structs/603/60373-71-9-7dfb.webp)

![(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure (2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure](https://static.chemtradehub.com/structs/109/1093085-91-6-3382.webp)
