Charge-transfer band shifts in iron(iii) hexacyanoferrate(ii) by electro-intercalated cationsvia ground state-energy/lattice-energy link

Literature Information

Publication Date 2002-11-08
DOI 10.1039/B209708G
Impact Factor 6.222
Authors

David R. Rosseinsky, Xiao Zhang, Hongjin Jiang, Jian Wei Chai


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Abstract

It is currently important to achieve and understand adjustments of optical properties: “guest cation” induced CT spectral shifts in Prussian Blue are shown to be driven (via its specific effect on the Fe(CN)6 CT-donor entity) by the cation lattice-energy interaction, as inferred from microgravimetry of introduced alkali-metal ions, and from independent solubility correlations for other intercalated cations.

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