Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(μ4-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

Literature Information

Publication Date 2002-11-08
DOI 10.1039/B209496G
Impact Factor 6.222
Authors

Carmen Soria Alvarez, Andrew D. Bond, Dale Cave, Marta E. G. Mosquera, Eilís A. Harron, Richard A. Layfield, Mary McPartlin, Jeremy M. Rawson, Paul T. Wood, Dominic S. Wright


View Original

Abstract

The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L1)4]2 (1) and [Mn8(L2)12(μ4-O)2] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.

Related Literature

Molecular insights into the binding variance of the SARS-CoV-2 spike with human, cat and dog ACE2 proteins

Yongjian Zang, Xuhua Li, Yizhen Zhao, He Wang, Dongxiao Hao, Lei Zhang, Zhiwei Yang, Xiaohui Yuan, Shengli Zhang

2021-06-03 Paper

DOI: 10.1039/D1CP01611C

Front cover

2021-06-16 Cover

DOI: 10.1039/D1CP90121D

Fabrication of high quality electrochemical SERS (EC-SERS) substrates using physical vapour deposition

Carolyn G. Farling, Mary C. Stackaruk, Cory C. Pye, Christa L. Brosseau

2021-07-14 Paper

DOI: 10.1039/D1CP02416G

Exceptionally high saturation magnetisation in Eu-doped magnetite stabilised by spin–orbit interaction

M. Hussein N. Assadi, José Julio Gutiérrez Moreno, Dorian A. H. Hanaor, Hiroshi Katayama-Yoshida

2021-09-02 Paper

DOI: 10.1039/D1CP02164H

Mechanistic implications of Li–S cell function through modification of organo-sulfur cathode architectures

Lisa Djuandhi, Neeraj Sharma, Bruce C. C. Cowie, Thanh V. Nguyen, Aditya Rawal

2021-06-14 Paper

DOI: 10.1039/D1CP01838H

Contents list

2021-06-16 Front/Back Matter

DOI: 10.1039/D1CP90122B

Experimental and DFT studies on oxygen release and migration mechanisms of LaAl-type perovskites as catalyst supports in biomass-to-H2 conversion

Tao Deng, Yujie Zheng, Changlei Qin, Zhiliang Ou, Hongqiang Xia, Zhonghui Zhang

2021-05-19 Paper

DOI: 10.1039/D1CP01372F

Umbrella inversion of ammonia redux

2021-09-10 Paper

DOI: 10.1039/D1CP01991K

Simple lattice model of self-assembling metal–organic layers of pyridyl-substituted porphyrins and copper on Au(111) surface

Anastasiia I. Fadeeva, Vitaly A. Gorbunov, Alexander V. Myshlyavtsev

2021-08-20 Paper

DOI: 10.1039/D1CP03111B

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.