Spin alignment of orthogonal π-radicals of directly meso-linked porphyrin arrays
Literature Information
Daiki Machida, Yutaka Senshu, Jotaro Nakazaki, Kazutaka Hirakawa, Feipeng Wu
High-spin states of poly-π-radical cations of directly meso-linked Zn(II)porphyrin arrays were observed by ESR spectroscopy because of the stabilization of the high-spin states by sterically orthogonal alignment of adjacent π-radicals.
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