Spin alignment of orthogonal π-radicals of directly meso-linked porphyrin arrays

Literature Information

Publication Date 2002-11-13
DOI 10.1039/B209172K
Impact Factor 6.222
Authors

Daiki Machida, Yutaka Senshu, Jotaro Nakazaki, Kazutaka Hirakawa, Feipeng Wu


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Abstract

High-spin states of poly-π-radical cations of directly meso-linked Zn(II)porphyrin arrays were observed by ESR spectroscopy because of the stabilization of the high-spin states by sterically orthogonal alignment of adjacent π-radicals.

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