A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(i)

Literature Information

Publication Date 2002-11-26
DOI 10.1039/B209071F
Impact Factor 6.222
Authors

Hidetaka Nakai, Yongjun Tang, Peter Gantzel, Karsten Meyer


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Abstract

The synthesis and characterisation of a thallium(I) triscarbene complex of the chelating, tripodal carbene ligand 1,3,5-{tris(3-tert-butylimidazol-2-ylideno)methyl}-2,4,6-trimethylbenzene is reported, in which the thallium ion is coordinated by three N-heterocyclic carbene donors in a distorted trigonal planar environment.

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