The first structural characterization and determination of the isomerization activation parameters of a chiral phosphatitanocene

Literature Information

Publication Date 2002-11-11
DOI 10.1039/B208945A
Impact Factor 6.222
Authors

T. Keith Hollis, Yi Joon Ahn, Fook S. Tham


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Abstract

The activation parameters (ΔG‡298 = 11.5 (±1.0) kcal mol−1, ΔH‡ = 16.3 (±3.0) kcal mol−1, ΔS‡ = 16 (±11) cal mol−1 K−1) have been determined for the rac to meso isomerization of a phosphametallocene, bis(3,4-dimethyl-2-phenylphospholyl)titanium dichloride, 2, which has been structurally characterized.

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