Novel bis-acac-O,O–Ir(iii) catalyst for anti-Markovnikov, hydroarylation of olefins operates by arene CH activation

Literature Information

Publication Date 2002-11-13
DOI 10.1039/B208680H
Impact Factor 6.222
Authors

Roy A. Periana, Xiang Y. Liu, Gaurav Bhalla


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Abstract

A novel, thermally stable, homogeneous Ir catalyst for the anti-Markovnikov, hydroarylation of olefins is shown to operate by arene CH activation via the formation of a bis-acac-O,O phenyl–Ir(III) species.

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