Catalytic insertion of diazo compounds into N–H bonds: the copper alternative

Literature Information

Publication Date 2002-11-11
DOI 10.1039/B207389G
Impact Factor 6.222
Authors

M. Esther Morilla, M. Mar Díaz-Requejo, Tomás R. Belderrain, M. Carmen Nicasio, Swiatoslaw Trofimenko, Pedro J. Pérez


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Abstract

The complexes TpXCu (TpX = homoscorpionate) catalyse the insertion of diazo compounds into nitrogen–hydrogen bonds of amines and amides, under very mild conditions, with quantitative yields being obtained with equimolar ratios of reactants.

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