Gas-phase reactions of rhenium-oxo species ReOn+, n = 0, 2–6, 8, with O2, N2O, CO, H2O, H2, CH4 and C2H4

Literature Information

Publication Date 2001-04-06
DOI 10.1039/B100538N
Impact Factor 3.676
Authors

Martin K. Beyer, Christian B. Berg, Vladimir E. Bondybey


View Original

Abstract

The reactions of ReOn+, n = 0, 2–6, 8, with the small molecules O2, N2O, CO, H2O, H2 , CH4 and C2H4, are studied by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry under single collision conditions on the timescale of seconds. The ReOn+ species are produced by laser vaporization of solid rhenium and pulsed supersonic expansion in a helium–oxygen mixture into high vacuum. A wide variety of reactions are observed, including methane activation and epoxidation reactions. Re+ reacts with ethylene by sequential dehydrogenation. ReO2+ and ReO4+ exhibit the most diverse reaction pathways, while ReO5+ almost exclusively undergoes ligand exchange. ReO6+ and ReO8+ are largely unreactive, the only efficient reactions observed are with ethylene and water. Both molecules seem to be able to directly attack the dioxygen ligands. The observed chemistry is governed by a fine interplay between available coordination sites and thermochemistry.

Related Literature

Mesoporous silica with Ia3d cubic structure and good thermal stability

Jiebin Pang, J. Eric Hampsey, Qingyuan Hu, Zhiwang Wu, Vijay T. John, Yunfeng Lu

2004-02-12 Communication

DOI: 10.1039/B316501A

The kinetics of propene and hexenepolymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states

Fuquan Song, Roderick D. Cannon, Manfred Bochmann

2004-02-05 Communication

DOI: 10.1039/B314845A

Recycling of the homogeneous Co-Jacobsen catalyst through solvent-resistent nanofiltration (SRNF)

H. Weyten, A. Buekenhoudt, L. E. M. Gevers, I. F. J. Vankelecom, P. A. Jacobs

2004-02-16 Communication

DOI: 10.1039/B312580G

Large macroscopic size changes in chemomechanical polymers with binding sites for metal ions

Hans-Jörg Schneider, Tianjun Liu

2003-11-13 Communication

DOI: 10.1039/B310939A

New magnetically responsive polydicarbazole-magnetite nanoparticles

Jean-Paul Lellouche, Nurit Perlman, Augustine Joseph, Senthil Govindaraji, Ludmila Buzhansky, Aline Yakir, Ian Bruce

2004-02-06 Communication

DOI: 10.1039/B309375A

Synthesis and characterization of novel chiral sulfonato–salen–manganese(iii) complex in a zinc–aluminium LDH host

Samiran Bhattacharjee, James A. Anderson

2004-02-04 Communication

DOI: 10.1039/B315325H

Template-free synthesis of single-crystalline cadmium nanotubes

Pingàn Hu, Yunqi Liu, Lei Fu, Lingchao Cao, Daoben Zhu

2004-02-04 Communication

DOI: 10.1039/B312708G

Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS–HS to LS–LS transition

Ben A. Leita, Boujemaa Moubaraki, Keith S. Murray, Jonathan P. Smith, John D. Cashion

2003-11-20 Communication

DOI: 10.1039/B311818E

You might also like

Compound Q&A

What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?

1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...

141290-59-71H-Indazole-6-carbon...
Compound Q&A

How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?

Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...

2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A

What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?

Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...

68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A

Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?

Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...

741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A

How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?

Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...

80714-39-22-Fluoro-6-hydrazino...
Compound Q&A

What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?

6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...

499214-11-86-Formyl-2-pyridinec...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A

How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?

9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...

29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A

How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?

1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...

1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A

How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?

Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...

671820-52-3Methyl 3-oxo-1,2,3,4...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.