Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS–HS to LS–LS transition

Literature Information

Publication Date 2003-11-20
DOI 10.1039/B311818E
Impact Factor 6.222
Authors

Ben A. Leita, Boujemaa Moubaraki, Keith S. Murray, Jonathan P. Smith, John D. Cashion


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Abstract

The dinuclear iron(II) complex [(pypzH)(NCSe)Fe(μ-pypz)2Fe(NCSe)(pypzH)].2H2O displays a single, sharp spin crossover transition between the [HS-HS] and [LS-LS] states and is structurally characterised above and below the T1/2 = 225 K value

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