Synthesis and characterization of novel chiral sulfonato–salen–manganese(iii) complex in a zinc–aluminium LDH host
Literature Information
Samiran Bhattacharjee, James A. Anderson
A novel heterogeneous catalyst, [Zn2.15Al0.86(OH)6.02] [Mn]0.19[C6H5COO]0.48·2H2O, where {[Mn] = chiral sulfonato−salen-manganese(III) complex, Na2MnC20H22N2S2O12Cl, intercalated into ZnII–AlIII layered double hydroxide host}, has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.
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