Synthesis and characterization of novel chiral sulfonato–salen–manganese(iii) complex in a zinc–aluminium LDH host

Literature Information

Publication Date 2004-02-04
DOI 10.1039/B315325H
Impact Factor 6.222
Authors

Samiran Bhattacharjee, James A. Anderson


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Abstract

A novel heterogeneous catalyst, [Zn2.15Al0.86(OH)6.02] [Mn]0.19[C6H5COO]0.48·2H2O, where {[Mn] = chiral sulfonato−salen-manganese(III) complex, Na2MnC20H22N2S2O12Cl, intercalated into ZnII–AlIII layered double hydroxide host}, has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.

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