Manganese(3+) chloride 2,2'-{1,2-ethanediylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenolate) (1:1:1) | CAS No. 81065-76-1

Manganese(3+) chloride 2,2'-{1,2-ethanediylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenolate) (1:1:1)

Basic Information

CAS Number

81065-76-1

Molecular Formula

C18H18ClMnN2O4

Molecular Weight

416.7 g/mol

AD

Basic Physical Properties

Solubility

H2O: soluble2mg/mL, clear (warmed)

COC1=CC=CC(=C1[O-])C=NCCN=CC2=C(C(=CC=C2)OC)[O-].[Cl-].[Mn+3]

InChI

InChI=1S/C18H20N2O4.ClH.Mn/c1-23-15-7-3-5-13(17(15)21)11-19-9-10-20-12-14-6-4-8-16(24-2)18(14)22;;/h3-8,11-12,21-22H,9-10H2,1-2H3;1H;/q;;+3/p-3/b19-11+,20-12+;;

InChIKey

YUZJJFWCXJDFOQ-GAMUHHASSA-K

Complexity

378

Safety Information

View Safety Information

GHS Hazard Pictograms

H302H302

Hazard Statement

H302 Harmful if swallowed
Acute toxicity, oral

Synonyms & References

English

  • SM5YJ88LTU
  • BCP08133
  • DTXSID801021732
  • Q27289277
  • ethylbisiminomethylguaiacol manganese chloride
  • EUK-134
  • E75935
  • Chloro[bis(3,3'-di-methoxysalicylic)ethylenediamine] manganese
  • EUK 134 ;EUK134;SALEN-MN
  • manganese(3+);2-methoxy-6-[2-[(3-methoxy-2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolate;chloride
  • Manganese, chloro((2,2'-(1,2-ethanediylbis((nitrilo-kappaN)methylidyne))bis(6-methoxyphenolato-kappaO))(2-))-, (sp-5-13)-
  • Ethylbisiminomethylguaiacol manganese chloride [INCI]
  • 81065-76-1
  • Manganese, chloro((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(6-methoxyphenolato))(2-)-N2,N2',O1,O1')-
  • s4261
  • UNII-SM5YJ88LTU
  • EUK 134
  • MANGANESE, CHLORO((2,2'-(1,2-ETHANEDIYLBIS((NITRILO-.KAPPA.N)METHYLIDYNE))BIS(6-METHOXYPHENOLATO-.KAPPA.O))(2-))-, (SP-5-13)-
  • Manganese,chloro[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[6-methoxyphenolato-kO]](2-)]-,(SP-5-13)-
  • Manganese,chloro[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[6-methoxyphenolato-kO]]...
  • SALEN-MN
  • (SP-5-13)-Chloro[[2,2′-[1,2-ethanediylbis[(nitrilo-?N)methylidyne]]bis[6-methoxyphenolato-KO]](2-)]-manganese
  • 2,2′-[1,2-Ethanediylbis(nitrilomethylidyne)]bis[6-methoxy-phenol manganese complex
  • Chloro[[2,2′-[1,2-ethanediylbis(nitrilomethylidyne)]bis[6-methoxyphenolato]](2-)-N2,N2′,O1,O1′]-manganese

MDL Number

MFCD08059577

FAQ

What are the physical and chemical properties of Manganese(3+) chloride 2,2'-{1,2-ethanediylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenolate) (CAS: 81065-76-1)?

This compound is a crystalline solid with a molecular weight of approximately 762.35 g/mol. It has limited solubility in water and is highly reactive with reducing agents. The compound exhibits coordination chemistry typical of transition metal complexes.

How is Manganese(3+) chloride 2,2'-{1,2-ethanediylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenolate) (CAS: 81065-76-1) typically synthesized?

This compound can be synthesized by the reaction of manganese(III) chloride with a 6-methoxyphenolate ligand in the presence of an ethanediylbis[nitrilo(E)methylylidene] ligand. The synthesis typically requires careful control of pH and temperature to achieve high yield and selectivity.

What industries use Manganese(3+) chloride 2,2'-{1,2-ethanediylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenolate) (CAS: 81065-76-1)?

This compound is primarily used in the field of analytical chemistry for developing sensors and as a precursor in polymer chemistry. It also finds applications in the pharmaceutical industry for the synthesis of certain organic compounds.

What precautions should be taken when handling Manganese(3+) chloride 2,2'-{1,2-ethanediylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenolate) (CAS: 81065-76-1)?

Proper personal protective equipment (PPE) including gloves, goggles, and a lab coat should be worn when handling this compound. It should be stored in a dry and well-ventilated area, and all procedures should be carried out in a fume hood to minimize inhalation risk. In case of spill, it is recommended to consult the safety data sheet (SDS) for appropriate cleanup procedures.

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