Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12)

Basic Information

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CAS Number

32993-05-8

Molecular Formula

C41H35ClP2Ru

Molecular Weight

726.2 g/mol

Chemical Classification

Fine Chemicals Dyes and Pigments Organic Dyes

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

135 °C (dec.)

SMILES

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C1=C[CH]C=C1.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru]

InChI

InChI=1S/2C18H15P.C5H5.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h2*1-15H;1-3H,4H2;1H;/q;;;;+1/p-1

InChIKey

ITWYMVPMADIWDM-UHFFFAOYSA-M

LogP

8.956100000000006

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

242

Safety Information

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Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

Sensitiveness

Air & Moisture Sensitive

Synonyms & References

English

Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Chlorocyclopentadienylbis(triphenylphosphine)rutenium(II)
32993-05-8
Bis(triphenylphosphine)(chloro)cyclopentadienylruthenium
AC-5527
AKOS025310720
Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
Cyclopentadienylbis(triphenylphosphine)ruthenium chloride
Cyclopentadienylbis(triphenylphosphine)ruthenium(II) Chloride
Chloro(cyclopentadienyl) bis(triphenylphosphine) ruthenium(II)
MFCD00075004
FT-0696282
Bis(triphenylphosphine)cyclopentadienylruthenium chloride
Chloro(Cydopentadienyl) bis (Triphenyl-
Chlorocyclopentadienylbis(triphenylphosphine)-ruthenium(II)
Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride
(Ph3P)2(cyclopentadienyl)RuCl
[ClRu(PPh3)2Cp]
[Cp(PPh3)2RuCl]
Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthe
chlorocyclopentadienylbis(triphenylphosphine)ruthenium
Chlorocyclopentadienylbis(triphenylphosphine)rutheniuM(II) 5GR
Chlorocyclopentadienylbis-(triphenylphosphino)-ruthenium
CpRu(PPh3)2Cl
Cyclopentadienyl
Ruthenium,chloro-p-cyclopentadienylbis(triphenylphosphine)-(8CI)
Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium
Chloro(h-cyclopentadienyl)bis(triphenylphosphine)ruthenium
Chloro(h5-2,4-cyclopentadien-1-yl)bis(triphenylphosphine)ruthenium
Chloro(h5-cyclopentadienyl)bis(triphenylphosphine)ruthenium
Chloro-p-cyclopentadienylbis(triphenylphosphine)ruthenium

MDL Number

MFCD14155709

FAQ

What are the physical and chemical properties of Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8)?

Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8) is a complex compound with a molecular weight of approximately 622.2 g/mol. It is poorly soluble in water but soluble in organic solvents like chloroform and ethanol. The compound exhibits moderate reactivity with typical transition metal complexes and can undergo substitution reactions. It crystallizes in an octahedral form.

How is Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8) typically synthesized?

Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8) is synthesized via a reaction between ruthenium(II) chloride and 1,3-cyclopentadiene in the presence of triphenylphosphine. The yield is typically around 70% with good selectivity. The reaction is performed under an inert atmosphere to prevent oxidation.

What industries use Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8)?

Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8) is used in the pharmaceutical industry for the synthesis of complex organic molecules, in polymer chemistry for doping and functionalization, in sensor technology for catalytic applications, and in semiconductor manufacturing for electronic materials.

What precautions should be taken when handling Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8)?

When handling Chloro(1,3-cyclopentadien-1-yl)ruthenium-triphenylphosphine(12) (CAS: 32993-05-8), ensure the use of personal protective equipment (PPE) including gloves, goggles, and a lab coat. Work in a well-ventilated area or a fume hood to minimize inhalation risk. Store the compound in a dry, cool place away from oxidizing agents. In case of spill, immediately clean up with appropriate safety measures and consult an SDS for detailed instructions.