1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1)

Basic Information

View in Editor

CAS Number

18498-01-6

Molecular Formula

C26H24Cl2CoP2

Molecular Weight

528.27 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

260 °C (dec.)

Boiling Point

514.8 °C at 760 mmHg

Water Solubility

Insoluble in water.

Flash Point

281.7 °C

SMILES

View in Editor

C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Co]Cl

InChI

InChI=1S/C26H24P2.2ClH.Co/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChIKey

SYTWXWRJCLAZFP-UHFFFAOYSA-L

LogP

6.628700000000008

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

339

Safety Information

View Safety Information

Hazard Statement

H302 Harmful if swallowed
Acute toxicity, oral

H312 Harmful in contact with skin
Acute toxicity, dermal

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H332 Harmful if inhaled
Acute toxicity, inhalation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

Hygroscopic

Synonyms & References

English

[1,2-BIS(DIPHENYPHOSPHINO)ETHANE]DICHLOROCOBALT(II)
CoCl2(dppe)
FT-0696292
COBALT(II) CHLORIDE; DIPHOS
F16628
Cobalt, dichloro[1,2-ethanediylbis[diphenylphosphine-kP]]-, (T-4)-
dichlorocobalt;2-diphenylphosphanylethyl(diphenyl)phosphane
18498-01-6
DTXSID20451530
[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II)
cobalt(2+);2-diphenylphosphanylethyl(diphenyl)phosphane;dichloride
Dichloro[ethylenebis[diphenylphosphine]]cobalt
MFCD00134173
BENZOICACID,2-IODYL,1-METHYLETHYLESTER
[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt( cento)
SCHEMBL666371
AKOS015914421
1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II)
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
Dichloro[bis(1,2-diphenylphosphino)ethane]cobalt(II)
dichlorocobalt - ethane-1,2-diylbis(diphenylphosphane) (1:1)
Cobalt,dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']-, (T-4)-
Cobalt, dichloro[ethylenebis[diphenylphosphine]]-(8CI)
(1,2-Bis(diphenylphosphino)ethane)dichlorocobalt
Dichloro[1,2-ethanediylbis[diphenylphosphine]]cobalt
Dichloro[bis(diphenylphosphino)ethane]cobalt
[1,2-Bis(diphenylphosphino)ethane]cobalt(II) chloride
ethane]dichlorocobalt(II)
(1,2-bis(diphenylphosphino)ethane)-dichlorocobalt
1,2-[Bis(diphenylphosphino)ethane]cobaltdichloride
[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ)

MDL Number

MFCD00134173

FAQ

What are the physical and chemical properties of 1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1) (CAS: 18498-01-6)?

1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1) is a crystalline compound with a molecular weight of approximately 632.5 g/mol. It has low solubility in water but is soluble in organic solvents like chloroform. This compound exhibits coordination chemistry typical of cobalt(II) complexes, showing reactivity in organic synthesis and catalysis contexts.

How is 1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1) (CAS: 18498-01-6) typically synthesized?

1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1) is synthesized by reacting dichlorocobalt with 1,2-bis(diphenylphosphino)ethane in an inert atmosphere. The reaction is typically conducted at room temperature and results in a high yield of the desired complex. This method provides good selectivity and is commonly used in the preparation of homogeneous catalysts.

What industries use 1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1) (CAS: 18498-01-6)?

1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1) is utilized in various industries, including pharmaceuticals for catalytic reactions, polymers for functionalization, and semiconductors for dopants. It is also used in sensor technologies for its reactivity and stability.

What precautions should be taken when handling 1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1) (CAS: 18498-01-6)?

When handling 1,2-Ethanediylbis(diphenylphosphine) - dichlorocobalt (1:1), it is crucial to use appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Storage should be done in a fume hood to minimize exposure. In case of a spill, immediately clean up in a well-ventilated area and follow the material safety data sheet (SDS) for proper disposal procedures.