Ethyl 2-(bromomethyl)acrylate

Basic Information

View in Editor

CAS Number

17435-72-2

Molecular Formula

C6H9BrO2

Molecular Weight

193.04 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Carboxylic Acids

Basic Chemical Raw Materials Organic Chemicals Esters

Basic Chemical Raw Materials Organic Chemicals Ethers

Basic Physical Properties

Physical State

Pale-yellow to Yellow-brown Liquid

Melting Point

134-136 ºC

Boiling Point

86°C/20mmHg

Refractive Index

n20/D 1.479(lit.)

SMILES

View in Editor

CCOC(=O)C(=C)CBr

InChI

InChI=1S/C6H9BrO2/c1-3-9-6(8)5(2)4-7/h2-4H2,1H3

InChIKey

MTCMFVTVXAOHNQ-UHFFFAOYSA-N

LogP

1.5006

Topological Polar Surface Area

26.3 Å²

Hydrogen Bond Donor/Acceptor

0 / 2

Complexity

120

Safety Information

View Safety Information

GHS Hazard Pictograms

H315

H319

H335

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

Sensitive to light, air, and heat,

Synonyms & References

English

17435-72-2
Ethyl 2-bromomethylacrylate
2-(Bromomethyl)acrylic Acid Ethyl Ester
2-Bromomethyl-acrylic acid ethyl ester
ethyl 2-(bromomethyl)prop-2-enoate
InChI=1/C6H9BrO2/c1-3-9-6(8)5(2)4-7/h2-4H2,1H
NSC215252
ethyl 2-(bromomethyl)propenoate
EN300-77465
2-BROMOMETHYLPROPENOIC ACID ETHYL ESTER
ethyl (2-bromomethyl)acrylate
ethyl 2-bromomethyl-2-propenoate
AMY39543
Ethyl2-(bromomethyl)acrylate
AKOS015950731
ethyl alpha-(bromomethyl) acrylate
2-Propenoic acid, 2-(bromomethyl)-, ethyl ester
B1820
2-(bromomethyl)-acrylic acid ethyl ester
NSC-215252
ethyl-2-bromomethylacrylate
MFCD00031518
Q63409763
FT-0637551
J-010981
SCHEMBL377096
ETHYL BROMOMETHACRYLATE
CS-W015793
DTXSID10309738
Ethyl 2-(bromomethyl)acrylate
Ethyl 2-(bromomethyl)acrylate, 98%

MDL Number

MFCD00031518

Customs Code

2916190090

FAQ

What are the physical and chemical properties of Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2)?

Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2) is a colorless to pale yellow liquid with a molecular weight of approximately 181.04 g/mol. It is slightly soluble in water and soluble in organic solvents like ethanol and acetone. This compound is highly reactive due to the presence of the bromomethyl group, making it suitable for various polymerization and functionalization reactions.

How is Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2) typically synthesized?

Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2) can be synthesized using acryloyl chloride and ethylamine as starting materials. The reaction involves the nucleophilic substitution of the acryloyl chloride with ethylamine, followed by a Williamson ether synthesis to form the bromomethyl group. This process typically yields a high purity product with good selectivity.

What industries use Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2)?

Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2) finds applications in the pharmaceuticals, polymers, and coatings industries. It is used as a monomer for the synthesis of various polymers and as a functional group in the preparation of specialty chemicals and pharmaceutical intermediates.

What precautions should be taken when handling Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2)?

When handling Ethyl 2-(bromomethyl)acrylate (CAS: 17435-72-2), it is essential to wear appropriate personal protective equipment (PPE), including gloves, goggles, and a lab coat. Work should be conducted in a well-ventilated area or a fume hood. Spills should be cleaned up with appropriate absorbent materials and disposed of according to local regulations. Always refer to the Safety Data Sheet (SDS) for detailed safety guidelines.