Iron tetraphenylporphine

Basic Information

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CAS Number

16591-56-3

Molecular Formula

C44H28FeN4

Molecular Weight

668.6 g/mol

Basic Physical Properties

SMILES

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C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C([N-]5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)[N-]3.[Fe+2]

InChI

InChI=1S/C44H28N4.Fe/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2

InChIKey

ZWYCMWUUWAFXIA-UHFFFAOYSA-N

Complexity

1330

Synonyms & References

English

16591-56-3
iron(2+);5,10,15,20-tetraphenylporphyrin-22,24-diide
Iron tetraphenylporphine
[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~4~N~21~,N~22~,N~23~,N~24~]iron
MQP
5,10,15,20-tetraphenyl-21h,23h-porphine iron(iii)chloride
Iron(III) 5,10,15,20-Tetrakis(4-methylphenyl)-21H,23H-porphine
IRON(II) MESO-TETRAPHENYLPORPHYRIN
,&#947
,&#948
[5,10,15,20-Tetraphenylporphinato(2-)]iron
Iron (II) tetraphenylprophyrin
Iron, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)-
Iron, [5,10,15,20-tetraphenylporphinato(2-)]-
Tetraphenylporphineiron(II)
-Tetraphenylporphyrinato(2-)]iron
IRON TPP
RARECHEM AS SA 0004
Iron tetraphenylporphyrin
PROTOPORPHYRIN IX FE(III) CHLORIDE
TETRAPHENYLPORPHYRIN IRON III CHLORIDE
IRON (III) TETRAPHENYLPORPHINE CHLORIDE

FAQ

What are the physical and chemical properties of Iron tetraphenylporphine (CAS: 16591-56-3)?

Iron tetraphenylporphine (CAS: 16591-56-3) is a crystalline compound with a molecular weight of approximately 557.27 g/mol. It is poorly soluble in water but soluble in organic solvents. Chemically, it is known for its ability to act as a Lewis acid and its role as an electron-donating ligand. It exhibits high reactivity towards coordination chemistry and redox properties.

How is Iron tetraphenylporphine (CAS: 16591-56-3) typically synthesized?

Iron tetraphenylporphine (CAS: 16591-56-3) is usually synthesized by the reaction of iron(II) chloride with tetraphenylporphyrin in the presence of a strong base such as sodium hydroxide. The yield is typically around 70%, and the reaction is exothermic, requiring careful control of temperature and pH to ensure selectivity and purity.

What industries use Iron tetraphenylporphine (CAS: 16591-56-3)?

Iron tetraphenylporphine (CAS: 16591-56-3) is used in various industries including pharmaceuticals for its role as a chelating agent, in polymers for its antioxidant properties, in sensors as a pigment, and in semiconductors for its electronic properties. It is also used in catalysis and as a model complex in coordination chemistry research.

What precautions should be taken when handling Iron tetraphenylporphine (CAS: 16591-56-3)?

When handling Iron tetraphenylporphine (CAS: 16591-56-3), it is crucial to wear appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Work should be conducted in a fume hood due to its potential volatility. Spills should be handled carefully, and cleaning should be done with appropriate solvents. Always consult the Safety Data Sheet (SDS) for specific guidelines and emergency procedures.