dichlororuthenium; [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-diphenyl-phosphane; 1-isopropyl-4-methyl-benzene

Basic Information

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CAS Number

145926-28-9

Molecular Formula

C54H46Cl2P2Ru

Molecular Weight

928.9 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

>100°C

SMILES

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CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl

InChI

InChI=1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChIKey

WNHLGYRPKARUHY-UHFFFAOYSA-L

LogP

3.99630

Complexity

886

Safety Information

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Hazard Statement

H340 May cause genetic defects
Germ cell mutagenicity

H360 May damage fertility or the unborn child
Reproductive toxicity

H371 May cause damage to organs
Specific target organ toxicity, single exposure

H373 Causes damage to organs through prolonged or repeated exposure
Specific target organ toxicity, repeated exposure

H402 Harmful to aquatic life
Hazardous to the aquatic environment, acute hazard

Sensitiveness

Air Sensitive

Synonyms & References

English

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride
[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium chloride, purum
MFCD00134456
F16612
SY071536
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride
Chloro[(R)-(+)-2,2 inverted exclamation mark -bis(diphenylphosphino)-1,1 inverted exclamation mark -binaphthyl](p-cymene)ruthenium(II) Chloride
Dichlororuthenium [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-diphenyl-phosphane 1-isopropyl-4-methylbenzene
D97679
AKOS015914587
dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene
SY073011
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
A888798
(R)-RuCl[(p-cymene)(BINAP)]Cl
[RuCl(p-cymene)((S)-binap)]Cl
Chloro[(S)-(-)-2,2 inverted exclamation mark -bis(diphenylphosphino)-1,1 inverted exclamation mark -binaphthyl](p-cymene)ruthenium(II) Chloride
[rucl((r)-binap)(p-cymene)]cl
CHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL] (P-CYMENE)RUTHENIUM(II) CHLORIDE
(S)-RuCl[(p-cymene(BINAP)]Cl
145926-28-9
130004-33-0
Ruthenium(1+),[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,chloride (1:1)
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
[RuCl(p-cymene)((R)-binap)]Cl
(R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Rutheniumchloride
[RuCl(p-cymene)((R)-binap)]Cl [RuCl(p-cymene)((R)-binap)]Cl
Ruthenium(1+),[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-met
Ruthenium(1+),[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1...
(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalenechloro(p-cymene)ruthenium chloride

MDL Number

MFCD00134456

Customs Code

28439000

FAQ

What are the physical and chemical properties of dichlororuthenium (CAS: 145926-28-9)?

Dichlororuthenium (CAS: 145926-28-9) is a purple solid with a molecular weight of approximately 297.03 g/mol. It has a low solubility in water but is soluble in organic solvents. The compound is relatively inert under normal conditions but can react with reducing agents. It crystallizes in the monoclinic system and is known for its catalytic properties in redox processes.

How is dichlororuthenium (CAS: 145926-28-9) typically synthesized?

Dichlororuthenium (CAS: 145926-28-9) can be synthesized via the chlorination of ruthenium(II) salts in the presence of chlorine gas. This process requires careful control of reaction conditions to achieve high selectivity and yield. Catalysts such as palladium or platinum can be used to improve the reaction efficiency.

What industries use dichlororuthenium (CAS: 145926-28-9)?

Dichlororuthenium (CAS: 145926-28-9) is used in the pharmaceutical industry for catalysts in organic synthesis, in the polymer industry for the production of functionalized polymers, and in the semiconductor industry for doping materials. It also finds applications in sensors for detecting various analytes.

What precautions should be taken when handling dichlororuthenium (CAS: 145926-28-9)?

When handling dichlororuthenium (CAS: 145926-28-9), appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat should be worn. This compound should be handled in a well-ventilated area or a fume hood to minimize exposure. Proper storage in a dry, cool place is essential, and spills should be cleaned up according to the safety data sheet (SDS) guidelines.