(E)-1,2-Ethenediylbis(tributylstannane)

Basic Information

View in Editor

CAS Number

14275-61-7

Molecular Formula

C26H56Sn2

Molecular Weight

606.1 g/mol

Chemical Classification

Polymers and Plastics Thermoplastics Polyolefins

Basic Physical Properties

Melting Point

180-182 ºC

Boiling Point

185°C 0,01mm

Water Solubility

Miscible with terahydrofuran and dimethyl formamide. Slightly miscible with water.

Flash Point

>110℃(>230℉)(lit.)

Solubility

Insuluble (4.2E-6 g/L) (25 ºC),

Refractive Index

1.503

SMILES

View in Editor

CCCC[Sn](CCCC)(CCCC)C=C[Sn](CCCC)(CCCC)CCCC

InChI

InChI=1S/6C4H9.C2H2.2Sn/c6*1-3-4-2;1-2;;/h6*1,3-4H2,2H3;1-2H;;

InChIKey

VNKOWRBFAJTPLS-UHFFFAOYSA-N

LogP

10.31920

Complexity

284

Safety Information

View Safety Information

Hazard Class

Class 6.1 Class 6.1

Sensitiveness

Air & Moisture Sensitive

Synonyms & References

English

14275-61-7
trans-1,2-Bis(tributylstannyl)ethene
tributyl-[(Z)-2-tributylstannylethenyl]stannane
DTXSID00418823
AKOS015843032
trans-1,2-bis(tri-n-butylstannyl) ethylene
J-524981
F11312
PROSTAGLANDINF3ALPHA
trans-1,2-Bis(tributylstannyl)ethylene
tributyl[(1E)-2-(tributylstannyl)ethenyl]stannane
(E)-1,2-Bis(tributylstannyl)ethene
trans-1,2-bis(tri-n-butylstannyl)ethylene
trans-1,2-Bis(tributylstannyl)ethene, 97%
MFCD01631299
Stannane, (1E)-1,2-ethenediylbis[tributyl-
GS-6197
(E)-1,2-bis-(tri-n-butylstannyl)-ethylene
C26H56Sn2
tributyl-[(E)-2-tributylstannylethenyl]stannane
Tributyl[(E)-2-(tributylstannyl)ethenyl]stannane #
Stannane, 1,2-ethenediylbis[tributyl-
Tributyl[(E)-2-(tributylstannyl)ethenyl]stannane
B1975
Bisbutylstannylethylene
trans-1,2-Bis(tri-n-butylstannyl)ethylene
BIS(TRI-n-BUTYLSTANNYL)ETHYLENE, trans isomer
trans-?1,?2-?Bis(tri-?n-?butylstannyl)?ethylene
TRANS-1,2-BIS(TRIBUTYLSTANNYL)ETHYLENE
(E)-1,2-Bis(tributylstannyl)ethylene
(E)-1,2-Bis(tributyltin)ethylene

MDL Number

MFCD01631299

FAQ

What are the physical and chemical properties of (E)-1,2-Ethenediylbis(tributylstannane) (CAS: 14275-61-7)?

(E)-1,2-Ethenediylbis(tributylstannane) is a colorless liquid with a high molecular weight of approximately 522.9 g/mol. It has a low solubility in water but is moderately soluble in organic solvents. The compound is known for its reactivity with various nucleophiles and is used in organic synthesis. Its physical properties include a boiling point of around 140°C and a melting point below 0°C.

How is (E)-1,2-Ethenediylbis(tributylstannane) (CAS: 14275-61-7) typically synthesized?

(E)-1,2-Ethenediylbis(tributylstannane) is typically synthesized via the Stille coupling reaction, using tributylstannane and (E)-1,2-dibromopropane as reactants. The reaction is catalyzed by palladium and usually proceeds with high selectivity and yield. This method is commonly used in organic synthesis to produce complex organostannane derivatives.

What industries use (E)-1,2-Ethenediylbis(tributylstannane) (CAS: 14275-61-7)?

(E)-1,2-Ethenediylbis(tributylstannane) is primarily used in the pharmaceutical and polymer industries due to its reactivity and ability to form stable organostannane compounds. It is also utilized in the production of sensors and semiconductors for its electronic properties. Its applications are mainly for organometallic chemistry and advanced material synthesis.

What precautions should be taken when handling (E)-1,2-Ethenediylbis(tributylstannane) (CAS: 14275-61-7)?

When handling (E)-1,2-Ethenediylbis(tributylstannane), use appropriate personal protective equipment (PPE) including gloves, goggles, and a lab coat. Work in a well-ventilated area or fume hood. Ensure proper storage in a cool, dry place away from oxidizing agents. In case of spill, consult the Safety Data Sheet (SDS) for disposal instructions and clean up using absorbent material. Always follow laboratory safety guidelines and safety regulations.