5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II)

Basic Information

View in Editor

CAS Number

14172-90-8

Molecular Formula

C44H28CoN4

Molecular Weight

671.65 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Heterocyclic Compounds

Pharmaceutical Chemicals Pharmaceutical Intermediates Heterocyclic Intermediates

Fine Chemicals Dyes and Pigments Organic Dyes

Laboratory Chemicals Research Chemicals Biochemical Reagents

Basic Physical Properties

Melting Point

>300 °C (dec.)

SMILES

View in Editor

c1ccc(cc1)/C/1=C/2\C=CC(=N2)/C(=c/2\n3[Co]n4c1ccc4/C(=C\1/C=CC(=N1)/C(=c\3/cc2)/c1ccccc1)/c1ccccc1)/c1ccccc1

InChI

InChI=1S/C44H28N4.Co/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34?,42-35-,42-37?,43-36-,43-38?,44-39-,44-40?;

InChIKey

LSZLYWSRWXFMOI-JJUIXLEHSA-N

LogP

7.564100000000007

Topological Polar Surface Area

34.58 Å²

Hydrogen Bond Donor/Acceptor

0 / 4

Complexity

934

Safety Information

View Safety Information

GHS Hazard Pictograms

H351

Hazard Statement

H351 Suspected of causing cancer
Carcinogenicity

Stability

Stable. Incompatible with strong oxidizing agents.

Synonyms & References

English

Cobalt,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-kN21,kN22,kN23,kN24]-, (SP-4-1)- (9CI)
Cobalt(II) meso-tetraphenylporphine
Cobalt(II) Tetraphenylporphyrin
cobalt(2+),5,10,15,20-tetraphenyl-1,4,5,10,11,14,15,20,21,23-decahydroporphyrin-22,24-diide
(Tetraphenylporphinato)cobalt
5,10,15,20-tetraphenyl-21H,23H-porphine Co(II)
5,10,15,20-Tetraphenyl-21H,23H-porphine Cobalt(II)
Co(II)
Cobalt chloride (CoCl3)
COBALT TPP
Cobalt trichloride
cobalt(II) 5,10,15,20-tetraphenylporphyrin
cobalt(II)-tetraphenylporphyrine
cobalt(III) chloride
Cobaltic chloride
cobalt-meso-tetraphenylporphyrin
CoII(tetraphenylporphyrin)
Kobalt(III)-chlorid
Cobalt(II) TPP
Co(II) meso-Tetraphenylporphine
RARECHEM AS SA 0002
PROTOPORPHYRIN IX CO (II)
COBALT TETRAPHENYLPORPHINE
TETRAPHENYLPORPHYRIN COBALT II
Cobalt meso-tetraphenylporphyrin
Cobalt(2+) tetraphenylporphinate
TPP-(Co2+)

MDL Number

MFCD00010725

Customs Code

29339900

FAQ

What are the physical and chemical properties of 5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) (CAS: 14172-90-8)?

5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) is a purple crystalline compound with a high molecular weight. It has low solubility in water but is soluble in organic solvents like ethanol. Chemically, it is relatively stable but can undergo photoreduction under intense light exposure. Its physical properties include a high melting point, which is typical of crystalline organic compounds.

How is 5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) (CAS: 14172-90-8) typically synthesized?

5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) is synthesized by the addition of cobalt(II) chloride to 5,10,15,20-tetraphenylporphine in the presence of a mild base such as sodium carbonate. The reaction is typically carried out in an inert solvent like tetrahydrofuran (THF) under reflux conditions. The yield is generally high, and the product is purified by recrystallization from an appropriate solvent.

What industries use 5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) (CAS: 14172-90-8)?

5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) finds applications in the pharmaceutical industry for its photodynamic properties, in the semiconductor industry for its electronic properties, and in sensor technology for its ability to respond to light. It is also used in polymer chemistry for its metal-ligand complexation ability.

What precautions should be taken when handling 5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) (CAS: 14172-90-8)?

Proper personal protective equipment (PPE) should be worn when handling 5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II), including gloves and goggles. Work should be conducted in a fume hood to minimize inhalation. Spills should be cleaned up using appropriate absorbent materials, and the site should be thoroughly washed down. The safety data sheet (SDS) should be consulted for detailed handling and disposal instructions. Avoid contact with skin and eyes, and store under inert conditions away from sources of heat and light.