Visible light-induced manganese-catalyzed aminocarbonylation of alkyl iodides under atmospheric pressure at room temperature
Literature Information
Yan-Hua Zhao, Xing-Wei Gu
Manganese catalysts, with advantages including low cost and relatively low toxicity, are attractive for application in carbonylation reactions. Herein, we report the synthesis of a series of amides via visible-light-induced manganese-catalyzed carbonylation of alkyl iodides using carbon monoxide as the C1 source. The reaction proceeds effectively at ambient temperature and pressure in the absence of ligands with a variety of alkyl iodides and aryl amines.
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Organic Chemistry Frontiers

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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