Nucleophilic organocatalysis involving radical intermediates

Literature Information

Publication Date 2023-10-17
DOI 10.1039/D3QO01435E
Impact Factor 5.281
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Abstract

The field of nucleophilic organocatalysis has garnered enormous interest and utility in the past two decades. Additionally, radical chemistry, mainly driven by the research progress in photocatalysis and electrocatalysis, has regained extensive attention. The unique reactivity of free radicals, which is different that of from closed-shell species, provides a solution to issues in electron-pair-mechanism-based catalysis. In this review, we highlight the advances in single-electron nucleophilic organocatalysis. We have separated the review into amine, N-heterocyclic carbene (NHC) and phosphine sections according to the type of organocatalyst. The strategies for the generation of radical species and the formation of new bonds are emphasized in the discussions of specific reactions. The final section provides a brief outline of the relationships among different nucleophilic organocatalysis and the prospects for future development.

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Source Journal

Organic Chemistry Frontiers

Organic Chemistry Frontiers
CiteScore: 7.8
Self-citation Rate: 8.7%
Articles per Year: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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