![2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure](https://static.chemtradehub.com/structs/567/56718-70-8-f037.webp "2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure")
Construction of a pillar[5]arene-based linear supramolecular polymer and a photo-responsive supramolecular network
Literature Information
Publication Date
2014-08-19
DOI
10.1039/C4PY01042F
Impact Factor
5.582
Authors
Jie Yang, Zhengtao Li, Yujuan Zhou, Guocan Yu
View Original
Abstract
A linear supramolecular polymer has been constructed from self-assembly of two complementary homoditopic monomers, an azobenzene-bridged pillar[5]arene dimer and a bisammonium salt, at high concentration based on the pillar[5]arene/secondary ammonium salt molecular recognition motif. This supramolecular polymer exhibited photo and pH dual-responsiveness. Polymer–oligomer and polymer–monomer transitions were reversibly regulated by UV/vis light irradiation and changing the solution pH, respectively. Furthermore, a photo-responsive supramolecular crosslinked liquid-crystalline polymer network based on the host–guest interactions between the azobenzene-bridged pillar[5]arene dimer and a secondary ammonium salt-functionalized poly(methyl acrylate) was fabricated.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione
CAS Number:
3089-17-6
Molecular Formula:
C20H10Cl2N2O2
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