Localized surface plasmon resonance assisted photoredox catalysis using newly fabricated copper-nanorods: a decarboxylative approach towards carbon–hydrogen bond formation under visible light
Literature Information
Publication Date
2023-11-28
DOI
10.1039/D3NJ04195F
Impact Factor
3.591
Authors
Saikat Khamarui, Sirshendu Ghosh
View Original
Abstract
The plasmonic behaviour of synthesized copper nanorods (Cu-NRs) plays an important role in redox processes as well as in coupling. A benign decarboxylative approach is developed to produce alkane analogues from corresponding alkyl carboxylic acids using these Cu-NRs via localised surface plasmon resonance (LSPR) assisted catalysis under visible light. A broad substrate scope and functional group tolerance are observed without any external oxidant or proton source. A plausible mechanism has also been proposed for this recyclable nano-catalyst based on some control experiments.
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Source Journal
New Journal of Chemistry
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3.7%
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NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.
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