High-rate cycling in 3D dual-doped NASICON architectures toward room-temperature sodium-metal-anode solid-state batteries
Literature Information
Sodium metal-based solid-state batteries hold tremendous potential for next-generation batteries owing to low-cost earth-abundant sodium resources. However, fabricating thin free-standing solid electrolytes that could cycle sodium at high current densities has been a major challenge in developing room temperature solid-state sodium batteries. By developing high conducting Zn2+ and Mg2+ dual-doped Na3Zr2SiPO12 (NASICON) solid electrolytes and fabricating a 3D porous-dense-porous architecture (with an ultrathin, 25 μm, dense separator) coated with a nanoscale ZnO layer, an extremely low anode interfacial resistance of 3.5 Ω cm2 was realized. This enabled a record high critical current density of 40 mA cm−2 at room temperature with no stack pressure and a cumulative sodium cycling capacity of 10.8 A h cm−2 was achieved. Furthermore, pouch cells were assembled as a proof-of-concept with Na3V2(PO4)3 cathodes on dense-porous bilayer electrolytes with sodium metal anodes and cycled up to 2C rates at room temperature with no applied stack pressure.
Related Literature
Orientation effects in morphology and electronic properties of anatase TiO2 one-dimensional nanostructures. I. Nanowires
Dmitri B. Migas, Andrew B. Filonov, Victor E. Borisenko
DOI: 10.1039/C3CP54988G
High-density biosynthetic fuels: the intersection of heterogeneous catalysis and metabolic engineering
Benjamin G. Harvey, Heather A. Meylemans, Raina V. Gough, Roxanne L. Quintana, Michael D. Garrison, Thomas J. Bruno
DOI: 10.1039/C3CP55349C
Electrodeposition of iron and iron–aluminium alloys in an ionic liquid and their magnetic properties
P. Giridhar, B. Weidenfeller, F. Endres
DOI: 10.1039/C4CP00613E
Crystal polymorphism: dependence of oxygen diffusion through 2D ordered Co nanocrystals
DOI: 10.1039/C3CP54656J
Photophysical and structural characterisation of in situ formed quantum dots
A. K. Bansal, F. Antolini, M. T. Sajjad, L. Stroea, S. G. Ramkumar, K.-J. Kass, S. Allard, U. Scherf, I. D. W. Samuel
DOI: 10.1039/C4CP00727A
Copper–amyloid-β complex may catalyze peroxynitrite production in brain: evidence from molecular modeling
Ilaria Ciofini, Li Rao, Christian Amatore
DOI: 10.1039/C3CP54839B
Operating mechanisms of electrolytes in magnesium ion batteries: chemical equilibrium, magnesium deposition, and electrolyte oxidation
Dong Young Kim, Younhee Lim, Basab Roy, Young-Gyoon Ryu, Seok-Soo Lee
DOI: 10.1039/C4CP01259C
A comparative structural study in monolayers of GPI fragments and their binary mixtures
C. Stefaniu, I. Vilotijevic, G. Brezesinski
DOI: 10.1039/C4CP00567H
Local silico-aluminophosphate interfaces within phosphated H-ZSM-5 zeolites
Hendrik E. van der Bij, Bert M. Weckhuysen
DOI: 10.1039/C3CP54791D
You might also like
What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?
1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...
How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?
Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...
What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?
Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...
Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?
Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...
How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?
Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...
What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?
6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...
What is the market or research trend for 3-(3,4-dimethoxyphenyl)-2,5-dimethyl-N-(2-morpholin-4-ylethyl)pyrazolo[1,5-a]pyrimidin-7-amine (CAS: 900874-91-1)?
Research trends for this compound indicate a focus on its potential applications...
How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?
9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...
How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?
1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...
How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?
Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...
Source Journal
Energy & Environmental Science

Energy & Environmental Science is an international journal dedicated to publishing exceptionally important and high quality, agenda-setting research tackling the key global and societal challenges of ensuring the provision of energy and protecting our environment for the future. The scope is intentionally broad and the journal recognises the complexity of issues and challenges relating to energy conversion and storage, alternative fuel technologies and environmental science. For work to be published it must be linked to the energy-environment nexus and be of significant general interest to our community-spanning readership. All scales of studies and analysis, from impactful fundamental advances, to interdisciplinary research across the (bio)chemical, (bio/geo)physical sciences and chemical engineering disciplines are welcomed. Topics include, but are not limited to, the following: Solar energy conversion and photovoltaics Solar fuels and artificial photosynthesis Fuel cells Hydrogen storage and (bio) hydrogen production Materials for energy systems Capture, storage and fate of CO2, including chemicals and fuels from CO2 Catalysis for a variety of feedstocks (for example, oil, gas, coal, biomass and synthesis gas) Biofuels and biorefineries Materials in extreme environments Environmental impacts of energy technologies Global atmospheric chemistry and climate change as related to energy systems Water-energy nexus Energy systems and networks Globally applicable principles of energy policy and techno-economics














![Sodium (2Z)-7-{[(2R)-2-amino-2-carboxyethyl]sulfanyl}-2-({[(1S)-2,2-dimethylcyclopropyl]carbonyl}amino)-2-heptenoate structure Sodium (2Z)-7-{[(2R)-2-amino-2-carboxyethyl]sulfanyl}-2-({[(1S)-2,2-dimethylcyclopropyl]carbonyl}amino)-2-heptenoate structure](https://static.chemtradehub.com/structs/811/81129-83-1-441c.webp)