Hosomi–Sakurai reactions of silacyclic allyl silanes

Literature Information

Publication Date 2006-05-02
DOI 10.1039/B602642G
Impact Factor 6.222
Authors

Jonathan D. Sellars, Patrick G. Steel, Michael J. Turner


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Abstract

Substituted silacyclohexenes, generated through silene–diene [4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres.

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