Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Literature Information

Publication Date 2023-12-20
DOI 10.1039/D3CC05391A
Impact Factor 6.222
Authors

Aiswarya Abhisek Mohapatra, Waleed Kuar Yual, Yadong Zhang, Anton Aleksandrovich Samoylov, Jonathan Thurston, Casey M. Davis, Declan P. McCarthy, Adam D. Printz, Erin L. Ratcliff, Neal R. Armstrong, Ann L. Greenaway


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Abstract

Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

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