Decarboxylative photoinduced ligand-to-metal charge transfer reaction: synthesis of 2-substituted chroman-4-ones

Literature Information

Publication Date 2023-12-29
DOI 10.1039/D3CC05331H
Impact Factor 6.222
Authors

Mohsen Monirialamdari, Anna Albrecht


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Abstract

In this manuscript, a photoinduced ligand-to-metal charge transfer (LMCT) approach, employing transition-metal-based photocatalysts, for the efficient alkylation of electron-poor olefin is described. The developed redox-neutral process benefits from mild reaction conditions and involves a wide range of chromone-3-carboxylic acids as well as nucleophiles amenable to selective C–H functionalization leading to the formation of 2-substituted chroman-4-one compounds with potential biological activity.

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