Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements viaproton-induced reversible metal migration
Literature Information
Christian Dubs, Akiko Inagaki, Munetaka Akita
Pairs of isomeric heterodinuclear complexes, [(cod)Ir(μ-PNNN)M(L)]BF4 and [(L)M(μ-PNNN)Ir(cod)]BF4, with switched metal arrangements are prepared in a specific manner by simply changing the addition order of the reagents.
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![7-Amino-5-methyl-5,7-dihydro-6H-dibenzo[b,d]azepin-6-one hydrochloride (1:1) structure 7-Amino-5-methyl-5,7-dihydro-6H-dibenzo[b,d]azepin-6-one hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/209/209984-32-7-9912.webp)


![6-Nitro-2-(4-nitrophenyl)imidazo[1,2-a]pyridine structure 6-Nitro-2-(4-nitrophenyl)imidazo[1,2-a]pyridine structure](https://static.chemtradehub.com/structs/118/118000-57-0-cb82.webp)
