Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements viaproton-induced reversible metal migration

Literature Information

Publication Date 2004-10-21
DOI 10.1039/B409514F
Impact Factor 6.222
Authors

Christian Dubs, Akiko Inagaki, Munetaka Akita


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Abstract

Pairs of isomeric heterodinuclear complexes, [(cod)Ir(μ-PNNN)M(L)]BF4 and [(L)M(μ-PNNN)Ir(cod)]BF4, with switched metal arrangements are prepared in a specific manner by simply changing the addition order of the reagents.

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