An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated “phosphaamidinate” anion

Literature Information

Publication Date 2004-09-28
DOI 10.1039/B408994D
Impact Factor 6.222
Authors

René T. Boeré, Marcus L. Cole, Peter C. Junk, Jason D. Masuda, Gotthelf Wolmershäuser


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Abstract

The reaction of DippPH2 (Dipp = 2,6-iPr2C6H3) with DippNC(p-CH3C6H4)Cl in refluxing xylenes affords DippPC(p-CH3C6H4)N(H)Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine.

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Inside front cover

Cover

DOI: 10.1039/D0SE90035D

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Back cover

Cover

DOI: 10.1039/D0SE90038A

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