An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated “phosphaamidinate” anion
Literature Information
René T. Boeré, Marcus L. Cole, Peter C. Junk, Jason D. Masuda, Gotthelf Wolmershäuser
The reaction of DippPH2 (Dipp = 2,6-iPr2C6H3) with DippNC(p-CH3C6H4)Cl in refluxing xylenes affords DippPC(p-CH3C6H4)N(H)Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine.
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