Dimerization of terminal alkynes catalyzed by a nickel complex having a bulky phosphineligand
Literature Information
Sensuke Ogoshi, Mizu Ueta, Masa-aki Oka, Hideo Kurosawa
Ni(cod)2/PtBu3 system catalyzed the dimerization of terminal alkynes to give (E)-head-to-head dimerization products, in which the stannylacetylene dimer could be applied to a one-pot synthesis of a conjugated enyne, when combined with Migita-Stille coupling.
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