Intramolecular C–N bond activation by a transient boryl anion

Literature Information

Publication Date 2023-11-09
DOI 10.1039/D3CC05182J
Impact Factor 6.222
Authors

Emily E. Nahon, Gareth R. Nelmes, Penelope J. Brothers, Jamie Hicks


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Abstract

Using a flexible diamido framework, a bulky boron bromide has been prepared as a precusor to a boryl anion with an extremely wide N–B–N angle. Reduction of the compound with lithium metal resulted in intramolecular C–N bond activation and migration of an aryl group onto the boron centre. Reaction of the boron bromide with K[FeCp(CO)2] resulted in nucleophilic reactivity of a carbonyl oxygen and the cooperative activation of CO.

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