Influence of donor point modifications on the assembly of chalcogen-bonded organic frameworks

Literature Information

Publication Date 2023-12-21
DOI 10.1039/D3CC05162E
Impact Factor 6.222
Authors

Brian J. Eckstein, Hannah R. Martin, Michael P. Moghadasnia, Arijit Halder, Michael J. Melville, Tara N. Buzinski, Gary J. Balaich, C. Michael McGuirk


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Abstract

Incremental, single-atom substitutions of Se-based chalcogen bond (Ch-bond) donors with stronger donating Te centers were implemented in two new triptycene tris(1,2,5-chalcogenadiazole) tectons. The appreciably more favorable Ch-bonding ability of the Te-based donors promotes assembly of low-density networks and more stable Ch-bonded organic frameworks (ChOFs).

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