Arylazopyrazole as a photo-switch for controllable self-assembly of pillar[6]arene-based supramolecular amphiphiles
Literature Information
Yishu Yu, Xiaotian Qu, Junran Li, Jie Yang
A photo-responsive host–guest molecular recognition between a cationic pillar[6]arene host and an arylazopyrazole derived guest was established. Based on this novel recognition motif, a photo-controllable supra-amphiphile was constructed. The spontaneous aggregation can be reversibly controlled by irradiation with UV (365 nm) and green light (520 nm), leading to a switch between spherical nanoparticles and vesicle-like aggregates.
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Chemical Communications

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