Photochemical reductive deamination of alpha-amino aryl alkyl ketones

Literature Information

Publication Date 2023-11-16
DOI 10.1039/D3CC04837C
Impact Factor 6.222
Authors


View Original

Abstract

Photochemical reductive deamination of alpha-amino aryl alkyl ketones under photosensitizer-free conditions is presented. This protocol features high efficiency and selectivity. A plausible reaction pathway is proposed based on ultraviolet–visible absorption investigation, control experiments and deuterium-labelling studies. Mechanistic study reveals that the alpha-hydrogen atom of the ketone product originated from water.

Related Literature

Contents list

Front/Back Matter

DOI: 10.1039/C4CP90005G

Modeling and simulation of the water gradient within a Nafion membrane

Masoumeh Ozmaian

2014-01-09 Paper

DOI: 10.1039/C3CP54015D

Theoretical and experimental studies of the interactions between Au2− and nucleobases

Hong-Guang Xu, Wei-Jun Zheng, Jun Li

2013-12-02 Paper

DOI: 10.1039/C3CP54478H

Folding and unfolding thermodynamics of the TC10b Trp-cage miniprotein

Charles A. English, Angel E. García

2013-12-17 Perspective

DOI: 10.1039/C3CP54339K

Graphene/g-C3N4 bilayer: considerable band gap opening and effective band structure engineering

Xinru Li, Ying Dai, Yandong Ma, Shenghao Han, Baibiao Huang

2014-01-06 Paper

DOI: 10.1039/C3CP54592J

Optimization of amorphous silicon double junction solar cells for an efficient photoelectrochemical water splitting device based on a bismuth vanadate photoanode

Lihao Han, Paula Perez Rodriguez, Bernard Dam, Miro Zeman, Arno H. M. Smets

2014-01-02 Paper

DOI: 10.1039/C3CP55035D

Mapping the structure of amyloid nucleation precursors by protein engineering kinetic analysis

David Ruzafa, Lorena Varela, Ana I. Azuaga, Francisco Conejero-Lara, Bertrand Morel

2013-12-06 Paper

DOI: 10.1039/C3CP54383H

Effects of process parameters on the defects in graphene oxide–polyaniline composites investigated by positron annihilation spectroscopy

Utpal Rana, P. M. G. Nambissan, Sudip Malik, Kuntal Chakrabarti

2013-12-16 Paper

DOI: 10.1039/C3CP54032D

Experimental and theoretical study of the electronic properties of Cu-doped anatase TiO2

Javier Navas, Antonio Sánchez-Coronilla, Teresa Aguilar, Desireé M. de los Santos, Jesús Sánchez-Márquez, David Zorrilla, Concha Fernández-Lorenzo, Rodrigo Alcántara, Joaquín Martín-Calleja

2013-11-25 Paper

DOI: 10.1039/C3CP54273D

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.