Reversing the ion transport selectivity through arm modification of an artificial molecular hourglass

Literature Information

Publication Date 2023-11-17
DOI 10.1039/D3CC04573K
Impact Factor 6.222
Authors

Wen-Long Huang, Xu-Dong Wang


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Abstract

An arm modification strategy, by replacing relatively rigid, electron-deficient side arms with flexible ether chain arms and linking them onto a tetraoxacalix[2]arene[2]triazine skeleton, was utilized to design an artificial molecular hourglass. The planar bilayer experiments confirmed the unimolecular channel mechanism and suggested reversed ion selectivity from the previously reported anion selectivity to weak cation selectivity.

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