Ammonia synthesis by the reductive N–N bond cleavage of hydrazine using an air-stable, phosphine-free ruthenium catalyst

Literature Information

Publication Date 2023-12-01
DOI 10.1039/D3CC04490D
Impact Factor 6.222
Authors

Aisa Mohanty, Smruti Rekha Rout, Rambabu Dandela, Prosenjit Daw


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Abstract

The development of an effective molecular catalyst to reduce hydrazine efficiently to ammonia using a suitable reductant and proton source is demanding. Herein, an unprecedented air-stable, phosphine-free ruthenium complex is used as a potent catalyst for hydrazine hydrate reduction to generate ammonia using SmI2 and water under ambient reaction conditions. Maximizing the flow of electrons from the reductant to the hydrazine hydrate via the metal centre results in a greater yield of ammonia while minimizing the evolution of H2 gas as a competing product.

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