Promoting nonsymmetric C–C coupling to valuable oxygenates without metal catalysts in alkali aqueous medium
Literature Information
Peidong Zhu, Chunling Wang, Heng Zhong, Yang Yang
Efficient conversion of C1 molecules into multicarbon oxygenates is a promising avenue for energy storage. Herein, we synthesize adjustable alkanoic acids/alcohols from formate C1 molecules via a hydrothermal reaction without any metal catalyst participation. This is achieved via HCO* and HCOO− nonsymmetric C–C coupling by alkali catalysis in aqueous medium.
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