Promoting nonsymmetric C–C coupling to valuable oxygenates without metal catalysts in alkali aqueous medium

Literature Information

Publication Date 2023-11-29
DOI 10.1039/D3CC04383E
Impact Factor 6.222
Authors

Peidong Zhu, Chunling Wang, Heng Zhong, Yang Yang


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Abstract

Efficient conversion of C1 molecules into multicarbon oxygenates is a promising avenue for energy storage. Herein, we synthesize adjustable alkanoic acids/alcohols from formate C1 molecules via a hydrothermal reaction without any metal catalyst participation. This is achieved via HCO* and HCOO− nonsymmetric C–C coupling by alkali catalysis in aqueous medium.

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