Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules
Literature Information
Publication Date
2020-04-06
DOI
10.1039/D0PY00369G
Impact Factor
5.582
Authors
Xun Zhang, Siping Hu, Qiang Ma
View Original
Abstract
The excited state acidity of ESPT molecules is first demonstrated as a suitable means of catalysis for the light-regulated ring-opening polymerization of lactones, in combination with a photosensitizer as the energy-transfer cocatalyst to harness light. Under blue light irradiation, this method could afford metal-free polyesters with well-controlled molecular weights and narrow dispersities.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Recommended Compounds
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1-(2-Chlorophenyl)-6-[(2S)-3,3,3-trifluoro-2-methylpropyl]-1,7-dihydro-4H-pyrazolo[3,4-d]pyrimidin-4-one
CAS Number:
794568-91-5
Molecular Formula:
C15H12ClF3N4O
![2-Methyl-2-propanyl [2-(2-oxa-6-azaspiro[3.3]hept-6-yl)ethyl]carbamate structure](https://static.chemtradehub.com/structs/141/1415562-38-7-c0a4.webp "2-Methyl-2-propanyl [2-(2-oxa-6-azaspiro[3.3]hept-6-yl)ethyl]carbamate structure")
2-Methyl-2-propanyl [2-(2-oxa-6-azaspiro[3.3]hept-6-yl)ethyl]carbamate
CAS Number:
1415562-38-7
Molecular Formula:
C12H22N2O3
6-Butyl-2-(2,4-difluorophenyl)-1,3,6,2-dioxazaborocane
CAS Number:
1190988-98-7
Molecular Formula:
C14H20BF2NO2
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