Mesoporous alloy chiral nanoparticles with high production yield and strong optical activities

Literature Information

Publication Date 2023-11-10
DOI 10.1039/D3CC04354A
Impact Factor 6.222
Authors

Yicong Ma, Lin Yang, Yu Chen, Xiaopeng Bai, Geping Qu, Tao Yao, Xiangchen Hu, Jianfang Wang, Zongxiang Xu, Yi Yu, Zhifeng Huang


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Abstract

Applying galvanic replacement reactions (GRRs) to the host chiral nanoparticles (CNPs) is an exclusive method to generate alloy CNPs with mesoporous structures through chirality transfer. However, the GRR-mediated chirality transfer is too inefficient to impose strong optical activities on the alloy mesoporous CNPs (or m-CNPs). Here we dope the host with gold (Au) to significantly enhance the chirality transfer, and additionally employ the Au adhesion layer to increase the production yield (PY) of binary m-CNPs.

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