Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient 15N NMR spectroscopy
Literature Information
Trent R. Graham, Yihui Wei, Eric D. Walter, Emily T. Nienhuis, Jaehun Chun, Gregory K. Schenter, Kevin M. Rosso, Aurora E. Clark
Predicting the behavior of oxyanions in radioactive waste stored at the Department of Energy legacy nuclear sites requires the development of novel analytical methods. This work demonstrates 15N pulsed field gradient nuclear magnetic resonance spectroscopy to quantify the diffusivity of nitrite. Experimental results, supported by molecular dynamics simulations, indicate that the diffusivity of free hydrated nitrite exceeds that of free hydrated sodium despite the greater hydrodynamic radius of nitrite. Investigations are underway to understand how the compositional and dynamical heterogeneities of the ion networks at high concentrations affect rheological and transport properties.
Related Literature
An automated computational approach to kinetic model discrimination and parameter estimation
Connor J. Taylor, Hikaru Seki, Friederike M. Dannheim, Mark J. Willis, Graeme Clemens, Brian A. Taylor, Thomas W. Chamberlain, Richard A. Bourne
DOI: 10.1039/D1RE00098E
UO2F2 particulate formation in an impinging jet gas reactor
Joshua A. Hubbard, Meng-Dawn Cheng, Lawrence Cheung, Jared R. Kirsch, Jason M. Richards, Glenn A. Fugate
DOI: 10.1039/D1RE00105A
A superamplification effect in the detection of explosives by a fluorescent hyperbranched poly(silylenephenylene) with aggregation-enhanced emission characteristics
Yongchun Zhong, Kam Sing Wong
DOI: 10.1039/C0PY00046A
Structured hydrophilic domains on silicone elastomers
Vinodh Rajendra, Yang Chen, Michael A. Brook
DOI: 10.1039/B9PY00220K
Detailed investigation of the propagation rate of urethane acrylates
Christopher Barner-Kowollik, Francesca Bennet, Maria Schneider-Baumann, Dominik Voll, Thomas Rölle, Thomas Fäcke, Marc-Stephan Weiser, Friedrich-Karl Bruder, Tanja Junkers
DOI: 10.1039/B9PY00352E
Thiol-ene and thiol-yne chemistry in microfluidics: a straightforward method towards macroporous and nonporous functional polymer beads
R. Arun Prasath, M. Talha Gokmen, Pieter Espeel, Filip E. Du Prez
DOI: 10.1039/C0PY00041H
Copper-catalyzed redox-neutral regioselective chlorosulfonylation of vinylarenes
Lixia Liu, Chengming Wang
DOI: 10.1039/D1RE00188D
Energy optimization of bio-oil production from biomass by fast pyrolysis using microwaves
Lilivet Ubiera, Isabelle Polaert, Michel Delmotte, Lokmane Abdelouahed, Bechara Taouk
DOI: 10.1039/D1RE00146A
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry












![(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure (2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure](https://static.chemtradehub.com/structs/109/1093085-91-6-3382.webp)

